I'm not really an expert when it comes to the anime style, but there are plenty of tutorials on this site. Simply search for "anime/manga tutorial" or something in that direction, and you're sure to find a lot of results
I do know a little more about digital art in general through. Drawing in MS Paint could be a struggle since it doesn't provide an option to enhance any quality unless you want huge files or doing pixel. Have you considered using another program? If money is an issue you can always use GIMP, which is free and contains a lot more functions than Paint Unless you have decided upon working only with pixels, of course.
Lmfao, oh man, you made my day. I live in Savannah, Georgia. In my school; it's uniforms. They are really stricted about stuff. The only way I can use GIMP if I get an administor's user and pass in which I know a pass of my assistant teacher's user, Mr. Barnes. I just need to get the user. Then, you can teach me then.